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Kathrin Schilling, Founder & Director, BioPowder, details how olive stones can be turned from a waste stream to high-performance functional powders for the coatings industry
All around the world and across industries, businesses are called to be more sustainable, green and clean. Hence, companies are increasingly required to balance economic, social and environmental considerations to ensure a better quality of life for current and future generations.
Amidst this push for sustainability, the paints and coatings industry may face some challenges due to the environmental and health impacts of some of the chemicals commonly used in its products. However, the market now provides natural, sustainable options that can even enhance physical and mechanical properties of coating formulations. These alternatives include bio-based binders, biodegradable texturisers, recycled content and natural pigments.
The incredibly useful olive
A circular raw material that has lately gained wider attention is the olive pit, a by-product from the olive oil mill. Olive oil manufacturing involves compressing of the whole olive, which produces a solid residue of pulp, peel and fragmented pits. In the past, raw olive pits have mainly been used for combustion. In some countries, they are still considered as waste products and not yet part of any upcycling value chain.
According to the International Olive Council[1], the global olive oil production volume for the 2021/22 crop year is estimated at 3.10 million metric tonnes, up 2.9% from the year before. Hence, there is a massive amount of olive pomace (pulp) left behind, which comes with certain disposal challenges because of its fat and polyphenolic compound content. Fortunately, new technologies have emerged to recover this waste stream and to break it down into its components.
Specialised machines are used to process the pomace in a moist state, and olive pit fragments are separated from pulp and shell through a centrifugation process. The fragments are then mechanically cleaned, dried and screened based on their particle sizes. Through this complex treatment process, BioPowder recovers light beige granules that are free of any dust/pulp and nearly odourless. BioPowder further processes them into top-grade micronised powders with different surface functionalisation options. Marketed under the brand name Olea FP, they are fully circular additives with desirable properties for modern coating formulations.
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Technical benefits of micronised performance powders from recycled olive stones
For paints, floorings and other coating systems, Olea FP present an exceptional range of opportunities thanks to the following mechanical properties:
- High hardness of >3.5 on the Mohs scale
Olea FP have a high level of hardness, making them suitable for use in coatings that require elevated strength, stability and abrasion resistance. This results in a long lifespan of functional coatings for outdoor and high-traffic areas.
- Low oil- and water-binding capacity
Due to their low oil- and water-binding capacity, Olea FP provide particle stability with no risk of swelling or expansion. This feature facilitates incorporation in both water- and solvent-based formulations, improves the durability of coatings and reduces the likelihood of cracking or peeling.
- Low density
Olea FP are low in density and therefore ideal for use in lightweight materials. This feature can also offer cost-saving potential by reducing the per-kg amount needed for volumetric batches.
- Compact particle shape
The compact particle shape of Olea FP allows for high predictability and ease of incorporation in coatings. The effect is generally a good dispersability leading to a smooth texture.
- Reactive particle surface
Surface reactivity of Olea FP can either be taken advantage of or suppressed through functionalisation. This feature allows for the production of coatings with tailored properties such as improved adhesion or water resistance.
- Thermal resistance and insulating properties
Olea FP have thermal resistance and insulating properties. This is particularly relevant for industrial coatings, e.g. for use in pipelines or storage tanks, where thermal resistance and insulation are critical.
Demonstrated effects of Olea FP in formulations
Reduction of gloss
One way in which Olea FP can enhance paint and coating formulations is by reducing their gloss. The micronised powders have proven effective as matting agents, among others in the following ways:
- As natural pigments in a PU-acrylate matrix: Olea FP was added to a PU-acrylate matrix to modify the colour and gloss of the coating. The addition of the powder resulted in a colour change towards the red/yellow spectrum and a gradual opacification of the paint. The overall gloss of the paint was reduced to nearly 50%, creating an increasingly matte finish.
- In replacement of polyethylene (PE) matting powders in acrylic paint formulations: a functionalised (hydrophobic) grade of Olea FP was added at a concentration of 10%. The comparative study showed a reduced gloss at all incident angles, with the 0-100 μm being most effective particle size range.
On the whole, the conducted studies demonstrate the effectiveness of Olea FP as a matting agent in various types of paint formulations, including epoxy and acrylic paints. By reducing the gloss of such coatings, Olea FP can help create a matte finish, which is desirable in many applications such as automotive or furniture coatings. Additionally, their use as replacements of traditional matting agents like PE powder can greatly reduce the environmental impact of coatings manufacturing.
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Reinforcement and enhanced abrasion resistance
The high hardness of Olea FP makes them ideal for use as reinforcing agents in coatings. By adding variable doses of Olea FPs, manufacturers can improve the coatings’ resistance to wear and tear, i.e. caused by impact and abrasion. This feature is particularly useful in applications where coatings are subjected to high levels of stress, such as in marine or industrial settings. As part of a comprehensive study, the following tests were conducted:
- Indentation tests: In a PU-acrylate coating reinforced with Olea FP particles, it was found that doses of olive stone powder as low as 5% could increase the hardness of a paint by up to 20%.
- Taber tests: The abovementioned PU-acrylate formulation with varying load percentages of Olea FP was subjected to rotating Taber wheels. The latter applied pressure on the surface, which gradually removed the coating layer. It was found that the use of olive stone powder reduced mass loss by up to 50% in less than 600 cycles.
These results demonstrate that olive stone powder improves the abrasion resistance and hardness of formulations. Consequently, Olea FP can help extend the lifespan of coatings, which ultimately boosts efficiency and supports less frequent use. Additionally, the powder’s feather-light properties make it an attractive option for lightweight coatings in applications where every gram counts.
Image caption: BioPowder’s reinforced linoleum ‘naturazzO’ is a resilient flooring solution that contains up to 40% of Olea FP composite fillers. It has been proven effective for high-load industrial surfaces
Natural particles for texture and surface effects
In addition to its use in matting and reinforcement, Olea FP are also an excellent option for creating unique surface textures in coatings. Manufacturers looking for bio-based alternatives can consider using Olea FP for the following uses:
- Functional filler and viscosity agent: Incorporating olive stone powder in epoxy, acrylic, or other formulations allows for viscosity and rheology adjustments while improving the overall strength of the formulation.
- Surface texture particles: Olive stone particles can be scattered on the surface of coatings to create a decorative and/or anti-slip effect. Olea FP texture particles are available in grain size ranges from <50μm up to 4mm, allowing for a large spectrum of texturing options.
- Decorative particles and pigment carriers: Besides being well suited for decorative effects, Olea FP texture particles are powerful pigment carriers. Tests have demonstrated high levels of effectiveness with pigments from both natural and synthetic sources. In response to the high demand for all-natural texture particles, e.g. as alternatives for quartz or polymer particles, BioPowder has recently launched its own colour particle range marketed under the brand Olea Colors.
Image caption: Manufacturers can create unique surface textures with BioPowder’s natural particles. Recommended systems for particle incorporation include epoxy, PU, and poly-aspartic resins
In sum, the use of Olea FP in coatings comes with multiple advantages. As a compostable material, it constitutes an eco-friendly alternative to conventional matting particles. Its resistance and lightweight properties make it an attractive reinforcing option, while its customizable micron ranges provide versatile surface texturing opportunities. Manufacturers would ideally take advantage of these effects in combination to create attractive design coatings from renewable sources.
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Bio-based functional powders: Green innovation with an optimised carbon footprint
The need of companies to adopt sustainability throughout their value chain has doubtlessly become imperative. But what does it take to be truly eco-friendly and set new standards for responsible manufacturing practices? Specifically, what makes a coating stand out as more sustainable? The answer lies in the carbon footprint, and hence a full life-cycle assessment, of all materials used in a formulation.
Measuring the CO2 output in all stages of the manufacturing value chain has become a recognised benchmark. In this regard, BioPowder has committed to lean practices that are deeply ingrained in the circular ecosystem of olive by-products. As a consequence, olive stone particles come with an optimised carbon footprint: they are manufactured 100% mechanically, i.e. with electricity being the main required utility. The use of water is minimal, and production does not generate any waste. Most remarkably, olive trees are among the plants that bind the largest amounts of CO2. Evidence shows that roughly 1.5kg of CO2 is produced per liter of extra virgin olive oil. However, an olive orchard can absorb up to 10kg of CO2 while growing the equivalent quantity of olives[2].
In conclusion, it can be said that olive stone powders are doubtlessly creating opportunities for carbon-efficient innovation in paints and coatings. The BioPowder team supports coatings manufacturers throughout all stages of R&D and production and looks forward to new project partners.
About BioPowder
BioPowder is a responsible producer and supplier of high-grade fruit stone powders and bio-based abrasives that are free of chemical additives. Derived from food processing side streams, the company’s products support a circular economy and enable manufacturers to reduce their environmental impact.
Founded in 2017 and headquartered in Malta, the company sources from the Mediterranean region and manages production in Southern Spain. BioPowder is part of a sustainable supply chain that strongly believes in processing agricultural by-products (not crops), sourcing locally or regionally, and ensuring that its activities do not disrupt the food chain.
For more information, please visit bio-powder.com.
[1] International Olive Council, The World of Olive Oil, 13 Jan 2022
[2] International Olive Council, Application for the Calculation of CO2 Balance in Olive Farming, 27 Jul 2016